I have a hard time choosing:
My favorite non-couple (so far) is Barney/Robin from How I Met Your Mother
My favorite canon TV couple is Tony/Angela from Who's The Boss?
Next favorite couples:
Mulder/Scully (X-Files)
Ross/Rachel (Friends)
Jim/ Pam (The Office)
Mike/Kate (Growing Pains)
Spike/ Buffy (Buffy, The Vampire Slayer)
Angel/Cordy (Angel)
There are more
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